Posts Tagged ‘Zylon’

Well, you asked, I listened. With all the mail volume I get, this single request was the most common. Thanks everyone for their patience, I have been extremely busy of late with travel, testing, evals, and even a tiny little bit of personal life. 🙂

When it became clear that Zylon was a huge liability and safety hazard in soft armor, lots of people wanted to know if their vests contained it. With the more recent realizations that first and second generation aramid laminates such as GoldFlex and GoldShield, and UHMWPE laminates such as Dyneema and Spectra have notable drawbacks and Achilles Heels, identifying these has also become important.

And so, without further ado, here is how you determine what kind of stuff your armor contains.

1. The first step is to field strip your armor. Most concealable vests today are multi-component, consisting of an outer shell or carrier, and an inner ballistic package. These are generally bottom-load, with the closure consisting of strips of hook and loop along the bottom seam. There are some manufacturers that use a top-load, and some that use a “mid-load” with a seam across the middle part of the vest. Regardless, determine how to get your ballistic panels out of the carrier, and we can get to the next part.

2. Look at your ballistic package. About 80-90% of modern vests will have the actual material encapsulated in some sort of secondary shell, usually consisting of GoreTex, or thin Nylon ripstop that has heat sealed edges. If this is the case, skip to part 4, since you will be using texture and feel to determine what you have.

3. If you have one of the 10-20% of vests that does not have the ballistic material encapsulated in a secondary shell, you will be able to use visual means of determining the composition. I have included closeups of the four materials found in vests to aid in identification:

100% Woven Kevlar- The Gold Standard for body armor

100% Woven Kevlar- The Gold Standard for body armor

A. Woven Kevlar- This is the material you want to see. It appears as a bright yellow fiber, with discernable warp and weft. Ideally, your armor consists of nothing but this.

GoldFlex- Not the most optimal material, but could be worse...

GoldFlex- Not the most optimal material, but could be worse…

B. Aramid Laminates- This material will have the same bright yellow appearance as woven Kevlar, but will not have any warp/weft. It will appear glossy, shiny, or slippery, due to the plastic film that covers it. Not optimal, but better than the next two.

UHMWPE- Milk Jugs with delusions of grandeur.

UHMWPE- Milk Jugs with delusions of grandeur.

C. UHMWPE Laminates- Either Spectra or Dyneema, this material will have a pearlescent, white, shiny/waxy appearance. Less desirable than aramids.

Zylon- "Danger, Will Robinson, danger!"

Zylon- “Danger, Will Robinson, danger!”

D. Zylon- DANGEROUS TO WEAR, this material is a liability and should immediately be discarded. Zylon, in its woven iterations, has a bright orange or bronze tint. In its laminate form, it will exhibit the same coloration, minus the weave pattern. Any armor containing Zylon should no longer be worn, and if possible discarded and replaced.

4. If your armor package is wrapped up in a secondary shell material, you have two options: see if there are any rips, tears, or holes in the material of the shell (to allow visual inspection), or rely on tactile sensitivity. The former is only possible if the armor is older, and there is existing wear or damage to the inner shell. Not an ideal circumstance. The latter will not allow you to determine the composition of the armor with very much accuracy, but is better than nothing.

Pull the shell material tight, and feel both the front and the back. If there is a detectable weave texture on both sides, you have a fairly good chance that the vest is made with 100% woven material. If older than 1990, it is MOST LIKELY woven Aramid, though there is a small chance it is Spectra Flex. If newer than 1998, there is a CHANCE it is made with woven Zylon. If you are worried this is the case, making a small slit in the shell material (if the inner shell is heat sealed) or using a seam ripper to pull about an inch and a half of the seam for visual inspection is advised. If handy with a needle and thread, this can be sewn up again.

If the material on one or both sides feels slick/slippery, then it indicates a laminate hybrid or 100% laminates respectively. Again, if it is of grave concern, a small inspection slit may be made in the inner shell. AGAIN, CUTTING A SLIT/RIPPING SEAMS SHOULD NOT BE DONE TO ARMOR THAT IS UNDER WARRANTY, AS THIS MAY VOID YOUR WARRANTY THROUGH THE MANUFACTURER.

Thus concludes the turorial. It will also be helpful to consult the label, and do a little research beforehand to see what materials you vest potentially contains. Hopefully this was helpful in determining your vest’s innards!

And, faithful readers, it is the first of several tutorials I intend to offer. Until next time!

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With the push to create ever-thinner, ever-lighter concealable body armor, companies cast about for materials that had even better strength-to-weight ratios than UHMWPE. In the late 90’s, they believed they had found a miracle material.

Developed in the late 80’s by SRI International, and marketed by Toyobo a Japanese company, PBO Zylon [poly(p-phenylene-2,6-benzobisoxazole)] promised to be the holy grail of the armor industry. With nearly TWICE the strength and Young’s Modulus of Aramid, and over twice the decomposition temperature (1202 F), Zylon looked to be a champion. Armor companies immediately started producing high-end vests using the new material. Within a short time, laminates began to be used as well, with names such as Z-Shield and Z-Flex.

The armors produced were impressive, unbelievable even. Thinner, lighter, and more comfortable than anything produced up until that time. Nearly a quarter of a million vests were produced before the shine came off the rose.

Despite the impressive statistics put up by Zylon fiber, these were “ideal” numbers. After time in the environment (especially the harsh conditions body armor is subjected to), it was found that Zylon degraded at a horrifying rate. Light and humidity exposure caused as much as a 60% decrease in the effectiveness WITHIN AS LITTLE AS SIX MONTHS. Due to how the fiber was finished (a phosphoric acid scouring process), small amounts of water (such as the vapor found in human sweat) could react with trace quantities of phosphoric acid remaining on the fibers, and trigger those acids to break down the fibers. UV light accelerated the breakdown.

These dangerous properties were brought to light in 2000 by a researcher at a major University, and CONFIRMED by Toyobo in 2001 (who, to their credit, had never recommended this fiber for use in body armor). These findings were dismissed, and Zylon continued to be used in soft armor.

If not for the tireless efforts of individuals such as Kevin “Mad Dog” McClung and Dr. Gary Roberts, this dangerous material may still be used in vests. This in spite of at least 3 deaths directly attributed to Zylon breakdown, leading to vests failing during bullet impacts.

After these high profile failures, and do to the revelations of Zylon’s unsuitability, a rush for the door ensued. Zylon was pulled by numerous manufacturers, and it was decertified by the NIJ for use in armor. The trouble is, a lot of these vests still remain in circulation today, either because the wearer was not made aware of the issue, or unscrupulous sellers feel that making a quick buck selling, essentially, garbage, is more important than the wearer’s safety.

Zylon should never, EVER be used in armor. If you have a vest that contains ANY, it is not safe, even if it is only a small portion. Identification of this material is paramount, and I will be posting a tutorial in a future post to allow people to determine what their armor consists of.

So avoid Zylon, at all costs, and stay safe!

Next time: We look at hard armor. Same time, same channel!